Attempted Low-Temperature Syntheses of Kaolin Minerals

Near-infrared Reflectance Spectra of Mixtures of Kaolin-group Minerals: Use in Clay Mineral Studies

-Near-infrared (NIR) reflectance spectra for mixtures of ordered kaolinite and ordered dickite have been found to simulate the spectral response of disordered kaolinite. The amount of octahedral vacancy disorder in nine disordered kaolinite samples was estimated by comparing the sample spectra to the spectra of reference mixtures. The resulting estimates are consistent with previously published...

Associated Minerals and their Influence on the Optical Properties of Jordanian Kaolin

Kaolin samples from Al-Disi kaolin deposits in southeastern region of Jordan are associated with mineral impurities, which impart color to this kaolin and adversely affect its application in paper and paint industries. The associated mineral impurities with kaolin were separated by deflocculating of kaolin particles in polymeric sodium polyphosphate solution. The crude kaolin, deflocculated kao...

Regioselective sulfamoylation at low temperature enables concise syntheses of putative small molecule inhibitors of sulfatases.

Regioselective sulfamoylation of primary hydroxyl groups enabled a 5-step synthesis (overall yield 17%) of the first reported small molecule inhibitor of sulfatase-1 and 2, ((2S,3R,4R,5S,6R)-4,5-dihydroxy-2-methoxy-6-((sulfamoyloxy)methyl)tetrahydro-2H-pyran-3-yl)sulfamic acid, which obviated the use of hydroxyl protecting groups and is a marked improvement on the reported 9-step synthesis (ove...

Room temperature syntheses of entirely diverse substituted β-fluorofurans.

Synthesis of highly substituted 3-fluorofurans is reported. The sequence began with preparation of tert-butyldimethylsilyl alk-1-en-3-yn-1-yl ethers from 1,4-disubstituted alk-3-yn-1-ones. Subsequent fluorination of alkenynyl silyl ethers with Selectfluor gave 2-fluoroalk-3-yn-1-ones in almost quantitative yield. Subsequent 5-endo-dig cyclizations using chlorotriphenylphosphine gold(I)/silver t...

Room temperature syntheses of entirely diverse substituted Î2-fluorofurans